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Alexander F. Hoffman

3 papers in the library · 77 citations · publishing 2016-2023

Papers

Disruption of hippocampal synaptic transmission and long‐term potentiation by psychoactive synthetic cannabinoid ‘Spice’ compounds: comparison with Δ9‐tetrahydrocannabinol

Addiction Biology January 5, 2016 Alexander F. Hoffman, Matthew D. Lycas, Jakub Kaczmarzyk et al. 39 citations

Synthetic cannabinoids found in 'Spice' products are potent activators of CB1 receptors in the mouse hippocampus, disrupting synaptic transmission and long-term potentiation (LTP). JWH-018 was the most potent inhibitor of hippocampal synaptic transmission (EC50 ~15 nM), followed by AM2201 (EC50 ~60 nM), while XLR-11 (EC50 ~900 nM) and Δ9-THC (EC50 ~700 nM) were much less potent. All effects were reversed by CB1 receptor antagonists, and AM2201 had no effect in mice lacking CB1 receptors. Exposure to any of these cannabinoids significantly impaired LTP, suggesting that synthetic cannabinoids can cause profound cognitive and behavioral deficits.

Positive Allosteric Modulation of the 5-HT1A Receptor by Indole-Based Synthetic Cannabinoids Abused by Humans

ACS Chemical Neuroscience April 23, 2020 Hideaki Yano, Pramisha Adhikari, Sett Naing et al. 26 citations

Synthetic cannabinoids (SCs) like AM2201 and JWH-018, but not the phytocannabinoid Δ9-tetrahydrocannabinol, act as positive allosteric modulators (PAMs) at the 5-HT1A receptor, a noncannabinoid site. In vitro, AM2201 potentiated 5-HT1A agonist-activated G protein-coupled inwardly rectifying potassium channel currents in neurons. In mice lacking cannabinoid receptor 1, AM2201 also potentiated the hypothermic response to 5-HT1A receptor stimulation. These findings suggest that PAM activity at 5-HT1A receptors may be a novel noncannabinoid mechanism contributing to the adverse effects of certain synthetic cannabinoids.

Subtle Structural Modification of a Synthetic Cannabinoid Receptor Agonist Drastically Increases its Efficacy at the CB1 Receptor

ACS Chemical Neuroscience October 17, 2023 Hideaki Yano, Rezvan Chitsazi, Christopher Lucaj et al. 12 citations

Minor chemical changes in synthetic cannabinoid receptor agonists (SCRAs) can dramatically increase their potency and efficacy at the CB1 receptor, making them far more toxic than THC. Using bioluminescence assays and hippocampal slice recordings, the authors found that adding a single methyl group to the head moiety of 5F-MMB-PICA (producing 5F-MDMB-PICA) greatly enhanced G protein signaling and β-arrestin recruitment. Molecular modeling showed how this small structural difference propagated to the receptor-G protein interface, explaining the heightened activity. These findings underscore the need for close surveillance of structural modifications in newly emerging SCRAs due to their potential for severe toxicity in humans.