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Deborah C Mash

7 papers in the library · 370 citations · publishing 1998-2022

Papers

Medication Development of Ibogaine as a Pharmacotherapy for Drug Dependencea.

Annals of the New York Academy of Sciences May 1, 1998 Deborah C Mash, Craig A Kovera, Billy E Buck et al. 111 citations

Ibogaine, an indole alkaloid from the rain forest shrub Tabernanthe iboga, has been used by indigenous peoples in equatorial Africa to combat fatigue and hunger and as a religious sacrament. Anecdotal reports from addict self-help groups claim a single dose eliminates withdrawal symptoms and reduces drug cravings for extended periods, but these purported antiaddictive properties require rigorous validation. A rising tolerance study with single administration has been initiated to assess ibogaine's safety for treating cocaine dependency, with primary objectives to determine safety, pharmacokinetics, dose effects, and relevant efficacy parameters. Pharmacokinetic and pharmacodynamic characteristics are assessed via concentration-time data from the Phase I trial and in vitro experiments on metabolism.

Ibogaine Detoxification Transitions Opioid and Cocaine Abusers Between Dependence and Abstinence: Clinical Observations and Treatment Outcomes.

Frontiers in pharmacology January 1, 2018 Deborah C Mash, Linda Duque, Bryan Page et al. 109 citations

A single oral dose of ibogaine, administered under medical supervision, diminishes opioid withdrawal symptoms and reduces drug cravings in people seeking to detoxify from opioids or cocaine. In an open-label case series of 191 human volunteers, no significant adverse events occurred at doses effective for blocking withdrawal. Pharmacokinetic measures from whole blood assays tracked ibogaine's metabolism and clearance. Multi-dimensional craving questionnaires showed reduced heroin and cocaine cravings during inpatient detoxification. One-month follow-up data suggested some persistence of craving reduction outside the inpatient setting. The results support developing ibogaine as a treatment for opioid withdrawal during medically supervised detoxification to transition individuals toward abstinence.

Noribogaine is a G-protein biased κ-opioid receptor agonist.

Neuropharmacology December 1, 2015 Emeline L Maillet, Nicolas Milon, Mari D Heghinian et al. 59 citations

Noribogaine, the main human metabolite of the anti-addictive substance ibogaine, reaches brain concentrations up to 20 μM after a therapeutic dose. Binding experiments and computational simulations indicate it may bind to the orthosteric morphinan site of opioid receptors. Noribogaine is a weak mu opioid receptor antagonist (Ke=20 μM at both G-protein and β-arrestin pathways) but a G-protein biased kappa opioid receptor agonist: 75% as efficacious as dynorphin A at stimulating GDP-GTP exchange (EC50=9 μM) yet only 12% as efficacious at recruiting β-arrestin. It also functionally inhibits dynorphin-induced kappa β-arrestin recruitment (IC50=1 μM), more potent than its G-protein agonism.

Oral noribogaine shows high brain uptake and anti-withdrawal effects not associated with place preference in rodents.

Journal of psychopharmacology (Oxford, England) July 1, 2016 Deborah C Mash, Barbara Ameer, Delphine Prou et al. 29 citations

Oral noribogaine dose dependently reduced naloxone-precipitated morphine withdrawal signs in mice by up to 88% with an ED50 of 13 mg/kg. Noribogaine showed high brain penetration with a brain/blood ratio of 7±1 across all doses tested. In rats, noribogaine up to 100 mg/kg did not produce conditioned place preference, indicating it is not perceived as a hedonic stimulus. Retrospective review of ibogaine studies suggests that differences in route of administration and testing time explain literature discrepancies. Noribogaine, not ibogaine, likely mediates withdrawal-blocking effects and may offer a non-addictive alternative to opiate replacement therapies.

Noribogaine reduces nicotine self-administration in rats.

Journal of psychopharmacology (Oxford, England) June 1, 2015 Qing Chang, Taleen Hanania, Deborah C Mash et al. 26 citations

Noribogaine, a drug that acts on opioid receptors, nicotinic receptors, and serotonin transporters, was tested for its ability to reduce nicotine self-administration in adult male rats. After training to self-administer nicotine intravenously, rats received oral doses of noribogaine (12.5, 25, or 50 mg/kg), vehicle, varenicline, or saline. Noribogaine dose-dependently decreased nicotine self-administration by up to 64% compared to saline-treated levels, matching the effectiveness of 1.7 mg/kg varenicline. At the highest dose, noribogaine reduced food pellet self-administration by only 23%, indicating greater specificity for nicotine. The findings suggest noribogaine may be a promising treatment for nicotine dependence.

Ibogaine analogues. Synthesis and preliminary pharmacological evaluation of 7-heteroaryl-2-azabicyclo[2.2.2]oct-7-enes.

Bioorganic & medicinal chemistry March 20, 2003 Daniele Passarella, Raffaele Favia, Alessandra Giardini et al. 23 citations

A method to synthesize 7-heteroaryl-2-azabicyclo[2.2.2]oct-7-enes using cycloaddition followed by cross-coupling is described. The binding affinity of these new compounds to the receptor targets characteristic of ibogaine is reported.

Structure-Activity Relationships of Dopamine Transporter Pharmacological Chaperones.

Frontiers in cellular neuroscience January 1, 2022 Charles Sutton, Erin Q Williams, Hoomam Homsi et al. 13 citations

Mutations in the dopamine transporter gene cause Dopamine Transporter Deficiency Syndrome (DTDS), a fatal infantile parkinsonism-dystonia with no current treatment. Pharmacological chaperones can rescue some disease-causing variants. This study examined structure-activity relationships for two known chaperones, bupropion and ibogaine. The isoquinuclidine substituent of ibogaine and its analogs is important for chaperone efficacy. For bupropion, the secondary amine group is essential. Additional analogs with varying chemical modifications showed variable chaperone efficacies, contributing to the design of improved dopamine transporter pharmacological chaperones.